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Metallodendrimer : ウィキペディア英語版
Metallodendrimer
A Metallodendrimer is a type of dendrimer with incorporated metal atoms. The development of this type of material is actively pursued in academia.
==Structure==
The metal can be situated in the repeat unit, the core or at the extremities as end-group. Elements often encountered are palladium and platinum. These metals can form octahedral six-coordinate M(IV) linking units from organic dihalides and the corresponding 4-coordinate M(II) monomers. Ferrocene-containing dendrimers and dendrimers with cobaltocene and arylchromiumtricarbonyl units have been reported in end-functional dendrimers.
Metallodendrimers can form as metal complexes with dendritic counter ions for example by hydrolysis of ester terminated PAMAM dendrimers with sodium hydroxide.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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