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|Section2= |Section3= }} Methylcyclopentadiene describes three isomeric cyclic diolefins with the formula C5MeH5 (Me = CH3). These isomers are the organic precursor to the methylcyclopentadienyl-ligand (C5H4Me, often denoted as Cp'), commonly found in organometallic chemistry. C5MeH5 is prepared by thermal cracking its Diels-Alder dimer, followed by distillation to remove cyclopentadiene C5H6, a common impurity. Relative to the corresponding Cp complexes, complexes of Cp' exhibit enhanced solubility in organic solvents. Furthermore, Cp' is often employed to probe the structure of organometallic complexes. For example, (MeC5H4)Fe(PPh3)(CO)I, exhibits four MeC5''H''4 resonances in its 1H NMR spectrum and five Me''C''5H4 resonances in the 13C NMR spectrum. Free rotation of the Cp' ligand does not equivalence the diastereopic protons and carbon centers. The achiral precursor complex (MeC5H4)Fe(CO)2)I exhibits only two MeC5''H''4 resonances in the 1H NMR spectrum and three Me''C''5H4 resonances in the 13C NMR spectrum. ==References== 〔 抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』 ■ウィキペディアで「Methylcyclopentadiene」の詳細全文を読む スポンサード リンク
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