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N-Sulfinylaniline : ウィキペディア英語版 | N-Sulfinylaniline
''N''-Sulfinylaniline is the organosulfur compound with the formula C6H5NSO. It is a straw-colored solid that is classified as a heterocumulene. It is prepared by treating aniline with thionyl chloride. An analogue of sulfur dioxide as well as sulfur diimide, it is a dienophile〔Kresze, G.; Wucherpfennig, W., "Organic synthesis with imides of sulfur dioxide", Angew. Chem., Int. Ed. Engl. 1967, volume 6, 149-167. 〕 and a ligand in organometallic chemistry.〔Hill, A. F., "Organotransition metallic chemistry of sulfur dioxide analogs", Adv. Organomet. Chem. 1994, 36, 159-227.〕 The structure of the related trityl derivative has been verified crystallographically.〔Christe, K. O.; Gerken, M.; Haiges, R.; Schneider, S.; Schroer, T.; Tham, F. S.; Vij, A., "Tritylsulfinylamine: a new member in the family of sulfinylamines", Solid State Sciences 2002, 4, 1529-1534. 〕 ==References== 〔
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