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Nitrapyrin
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・ Nitrate ester
・ Nitrate Kisses
・ Nitrate reductase
・ Nitrate reductase (cytochrome)
・ Nitrate reductase (NAD(P)H)
・ Nitrate reductase (NADH)


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Nitrapyrin : ウィキペディア英語版
Nitrapyrin

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Nitrapyrin is an organic compound with the formula ClC5H3NCCl3. It is a widely used nitrification〔Meta-analysis of Enhanced Efficiency Fertilizers in Corn, wheat, and sorghum in the Midwest http://research.ipni.net/page/RNAP-6379〕 inhibitor in agriculture 〔Heinrich Dittmar, Manfred Drach, Ralf Vosskamp, Martin E. Trenkel, Reinhold Gutser, Günter Steffens "Fertilizers, 2. Types" In: ''Ullmann's Encyclopedia of Industrial Chemistry''. Wiley-VCH, 2009, 〕 as well as a soil bactericide and has been in use since 1974. Nitrapyrin was put up for review by the EPA and deemed safe for use in 2005. Since nitrapyrin is an effective nitrification inhibitor to the bacteria nitrosomonas it has been shown to drastically the reduce NO2 emissions of soil.〔 Nitrapyrin is a white crystalline solid with a sweet odor and is often mixed with anhydrous ammonia for application.
==Synthesis==
Nitrapyrin is commonly produced by the photochlorination of 2-methylpyridine:〔S. J. Powell, J. I. Prosser “Inhibition of Ammonium Oxidation by Nitrapyrin in Soil and Liquid Culture“ Appl Environ Microbiology 1986, vol. 52, 782–787.〕
:CH3-C5H4N + 2Cl2 → CCl3-ClC5H3N + 4 HCl
Produced by DOW Chemicals, the product marketed under the trade name N-Serve and contains small amounts (less than 5% wt) of the non-active ingredient 4,6-dichloro-2-trichloromethylpyridine.

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