翻訳と辞書 Words near each other ・ Nitrophosphate process ・ Nitric-oxide synthase (NAD(P)H-dependent) ・ Nitrica ・ Nitride ・ Nitriding ・ Nitridoborate ・ Nitrification ・ Nitrifying bacteria ・ Nitrilase ・ Nitrile ・ Nitrile anion ・ Nitrile hydratase ・ Nitrile reduction ・ Nitrile rubber ・ Nitrile ylide ・ Nitrilimine ・ Nitriliruptoridae ・ Nitrilium ・ Nitrilotriacetate monooxygenase ・ Nitrilotriacetic acid ・ Nitrite ・ Nitrite dismutase ・ Nitrite oxidoreductase ・ Nitrite reductase ・ Nitrite reductase (NAD(P)H) ・ Nitrite reductase (NO-forming) ・ Nitrite test ・ Nitrium ・ Nitro ・ Nitro (Adlabs Imagica) Dictionary Lists mini英和辞書 mini和英辞書 Webster 1913 Latin-English FOLDOC Wikipedia English ウィキペディア

翻訳と辞書　辞書検索 [ 開発暫定版 ] スポンサード リンク Nitrilimine ： ウィキペディア英語版 Nitrilimine Nitrilimines or nitrile amides are a class of organic compounds sharing a common functional group with the general structure R-CN-NR corresponding to the conjugate base of an amine bonded to the N-terminus of a nitrile. The dominant structure for the parent compound nitrilimine is that of the propargyl-like 1 in ''scheme 1'' with a C-N triple bond and with a formal positive charge on nitrogen and two lone pairs and a formal negative charge on the terminal nitrogen. Other structures such as hypervalent 2, allene-like 3, allylic 4 and carbene 5 are of lesser relevance. Nitrilimines were first observed in the thermal decomposition of 2-tetrazoles releasing nitrogen:〔Communications: ''The Formation of Nitrile Imines in the Thermal Breakdown of 2,5-Disubstituted Tetrazoles Rolf Huisgen'' Michael Seidel, Juergen Sauer, James McFarland, Guenter WallbillichJ. Org. Chem.; 1959; 24(6); 892-893 (Abstract )〕 Nitrilimines are linear 1,3-dipoles represented by structures 1 and 3. A major use is in heterocyclic synthesis. E.g. with alkynes they generate pyrazoles in a 1,3-dipolar cycloaddition. Due to their high energy, they are usually generated ''in situ'' as a reactive intermediate. == References == 〔 抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』 ■ウィキペディアで「Nitrilimine」の詳細全文を読む スポンサード リンク 翻訳と辞書 : 翻訳のためのインターネットリソース Copyright(C) kotoba.ne.jp 1997-2016. All Rights Reserved.