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P-Phenylenediamine : ウィキペディア英語版
P-Phenylenediamine

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''p''-Phenylenediamine (PPD) is an organic compound with the formula C6H4(NH2)2. This derivative of aniline is a white solid, but samples can darken due to air oxidation.〔 It is mainly used as a component of engineering polymers and composites. It is also an ingredient in hair dyes.
==Production==
PPD is produced via three routes. Most commonly, 4-nitrochlorobenzene is treated with ammonia and the resulting 4-nitroaniline is then hydrogenated:
:ClC6H4NO2 + 2 NH3 → H2NC6H4NO2 + NH4Cl
:H2NC6H4NO2 + 3 H2 → H2NC6H4NH2 + 2 H2O
In the DuPont route, aniline is converted to diphenyltriazine, which is converted by acid-catalysis to 4-aminoazobenzene. Hydrogenation of the latter affords PPD.〔Robert A. Smiley "Phenylene- and Toluenediamines" in ''Ullmann's Encyclopedia of Industrial Chemistry'', 2002, Wiley-VCH, Weinheim. 〕

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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