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・ Phenacyl bromide
・ Phenacyl chloride
・ Phenadoxone
・ Phenaglycodol
・ Phenagoniates macrolepis
・ Phenakistoscope
・ Phenakite
・ Phenakospermum
・ Phenalene
・ Phenamidine
・ Phenampromide
・ Phenanthrene
・ Phenanthrenoid
・ Phenanthridine
・ Phenanthriplatin
Phenanthroline
・ Phenaridine
・ Phenatoma
・ Phenatoma novaezelandiae
・ Phenatoma rosea
・ Phenatoma zealandica
・ Phenazepam
・ Phenazine
・ Phenazocine
・ Phenazone
・ Phenazopyridine
・ Phenbenzamine
・ Phencyclamine
・ Phencyclidine
・ Phencyclidine (data page)


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Phenanthroline : ウィキペディア英語版
Phenanthroline

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Phenanthroline (phen) is a heterocyclic organic compound. It is a white solid that is soluble in organic solvents. It is used as a ligand in coordination chemistry, it forms strong complexes with most metal ions.〔 In terms of its coordination properties, phen is similar to 2,2'-bipyridine (bipy).
==Synthesis==
Phenanthroline may be prepared by two successive Skraup reactions of glycerol with ''o''-phenylenediamine, catalyzed by sulfuric acid, and an oxidizing agent, traditionally aqueous arsenic acid or nitrobenzene. Dehydration of glycerol gives acrolein which condenses with the amine followed by a cyclization.

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