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翻訳と辞書　辞書検索 [ 開発暫定版 ] スポンサード リンク Phenylsilane ： ウィキペディア英語版 Phenylsilane |Section2= |Section4= }} Phenylsilane, also known as silylbenzene, a colorless liquid, is one of the simplest organosilanes with the formula C6H5SiH3. It is structurally related to toluene, with a silyl group replacing the methyl group. Both of these compounds have similar densities and boiling points due to these similarities. Phenylsilane is soluble in organic solvents. ==Synthesis and reactions== Phenylsilane is produced in two steps from Si(OEt)4. In the first step, phenylmagnesium bromide is added to form Ph-Si(OEt)3 via a Grignard reaction. Reduction of the resulting Ph-Si(OEt)3 product with LiAlH4 affords phenylsilane.〔Minge, O.; Mitzel, N. W.; and Schmidbaur, H. Synthetic Pathways to Hydrogen-Rich Polysilylated Arenes from Trialkoxysilanes and Other Precursors. Organometallics 2002, 21, 680-684. 〕 :Ph-MgBr + Si(OEt)4 → Ph-Si(OEt)3 + MgBr(OEt) :4 Ph-Si(OEt)3 + 3 LiAlH4 → 4 Ph-SiH3 + 3 LiAl(OEt)4 抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』 ■ウィキペディアで「Phenylsilane」の詳細全文を読む スポンサード リンク 翻訳と辞書 : 翻訳のためのインターネットリソース Copyright(C) kotoba.ne.jp 1997-2016. All Rights Reserved.