翻訳と辞書 Words near each other ・ Phosphatidylinositol transfer protein ・ Phosphatidylinositol transfer protein, alpha ・ Phosphatidylinositol-3,4,5-trisphosphate 3-phosphatase ・ Phosphatidylinositol-3,4,5-trisphosphate 5-phosphatase ・ Phosphatidylinositol-3,4-bisphosphate 4-phosphatase ・ Phosphatidylinositol-3-phosphatase ・ Phosphatidylinositol-4,5-bisphosphate 3-kinase ・ Phosphatidylinositol-4,5-bisphosphate 4-phosphatase ・ Phosphatidylinositol-4-phosphate 3-kinase ・ Phosphatidylmyo-inositol mannosides ・ Phosphatidylserine ・ Phosphatidylserine decarboxylase ・ Phosphatocopida ・ Phosphatodraco ・ Phosphatosaurus ・ Phosphatrioxa-adamantane ・ Phosphaturic mesenchymal tumor ・ Phosphazene ・ Phosphene ・ Phosphene Dream ・ Phosphichthys ・ Phosphide ・ Phosphila ・ Phosphinate ・ Phosphine ・ Phosphine oxide ・ Phosphinidene ・ Phosphinimide ligands ・ Phosphinite ・ Phosphinoimidate Dictionary Lists mini英和辞書 mini和英辞書 Webster 1913 Latin-English FOLDOC Wikipedia English ウィキペディア

翻訳と辞書　辞書検索 [ 開発暫定版 ] スポンサード リンク Phosphatrioxa-adamantane ： ウィキペディア英語版 Phosphatrioxa-adamantane Phosphatrioxa-adamantane is an organophosphorus compound that is used as a precursor to bulky phosphine ligands.〔Paul G. Pringle, Martin B. Smith "Phosphatrioxa-adamantane Ligands" in Phosphorus(III) Ligands in Homogeneous Catalysis: Design and Synthesis, Edited by Paul C. J. Kamer and Piet W. N. M. van Leeuwen, 2012 John Wiley, New York. 〕 Abbreviated CgPH (for cage phosphine), it is a white solid. The compound is prepared by the condensation of two equivalents of acetylacetone and phosphine: :PH3 + 2 CH3C(O)CH2C(O)CH3 → HP(CH3CCH2CCH3)2O3 + H2O The condensation is sometimes called the Buckler–Epstein reaction. Many diketones can be employed in place of acetylacetone. The P-H bond can be further derivitized, leading to a range of tertiary phosphines of potential value in homogeneous catalysis. ==References== 〔 抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』 ■ウィキペディアで「Phosphatrioxa-adamantane」の詳細全文を読む スポンサード リンク 翻訳と辞書 : 翻訳のためのインターネットリソース Copyright(C) kotoba.ne.jp 1997-2016. All Rights Reserved.