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Phosphinite
Phosphinites are organophosphorus compounds with the formula P(OR)R2. They are used as ligands in homogeneous catalysis and coordination chemistry.〔D. E. C. Corbridge "Phosphorus: An Outline of its Chemistry, Biochemistry, and Technology" 5th Edition Elsevier: Amsterdam 1995. ISBN 0-444-89307-5.〕 ==Preparation== Phosphinites are prepared by alcoholysis of organophosphinous chlorides. For example, treatment of chlorodiphenylphosphine with methanol and base gives methyl diphenylphosphonite: :ClPPh2 + CH3OH → CH3OPPh2 + HCl Although they are esters of phosphinous acids (R2POH), phosphinites are not made via such intermediates.
抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)』 ■ウィキペディアで「Phosphinite」の詳細全文を読む
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