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Phosphinoimidate : ウィキペディア英語版 | Phosphinoimidate
Phosphinoimidates, also known as phophinimides, are anionic ligands of the form ()− (R = alkyl or aryl). They form transition metal complexes that are highly active catalysts in some olefin polymerization reactions.〔Dehnicke, K.; Krieger, M.; Massa, W. Phosphoraneiminato complexes of transition metals. Coord. Chem. Rev. 1999, vol. 182, pp. 19-65. 〕 ==Synthesis of phosphinoimidate complexes== Although phosphinoimidates are formally anions, salts of the anions are typically unavailable owing to their high basicity. Instead the ligand is installed indirectly.
抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)』 ■ウィキペディアで「Phosphinoimidate」の詳細全文を読む
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