翻訳と辞書
Words near each other
・ Phrynosomimus
・ Phrynus
・ Phrynus longipes
・ Phrynus marginemaculatus
・ Phrypeus
・ Phryssonotus
・ Phryxe
・ Phryxus
・ Phryxus (moth)
・ PHS
・ PHS1
・ PHSCologram
・ PHT
・ Pht01
・ PHTF2
Phthalaldehyde
・ Phthalane
・ Phthalate
・ Phthalate 4,5-cis-dihydrodiol dehydrogenase
・ Phthalate 4,5-dioxygenase
・ Phthalazine
・ Phthalic acid
・ Phthalic anhydride
・ Phthalide
・ Phthalimide
・ Phthalimidopropiophenone
・ Phthalocyanine
・ Phthalocyanine Blue BN
・ Phthalocyanine Green G
・ Phthalonitrile


Dictionary Lists
翻訳と辞書 辞書検索 [ 開発暫定版 ]
スポンサード リンク

Phthalaldehyde : ウィキペディア英語版
Phthalaldehyde

|Section2=
|Section7=
}}
''o''-Phthalaldehyde or ''ortho''-phthalaldehyde (OPA) is the chemical compound with the formula C6H4(CHO)2. Often abbreviated OPA, the molecule is a dialdehyde, consisting of two formyl (CHO) groups attached to adjacent carbon centres on a benzene ring. This pale yellow solid is a building block in the synthesis of heterocyclic compounds and a reagent in the analysis of amino acids. OPA dissolves in water solution at pH < 11.5. Its solutions degrade upon UV illumination and exposure to air.
==Synthesis and reactions==
The compound was first described in 1887 when it was prepared from α,α,α’,α’-tetrachloro-ortho-xylene. A more modern synthesis is similar: the hydrolysis of the related tetrabromoxylene using potassium oxalate, followed by purification by steam distillation.〔
The reactivity of OPA is complicated by the fact that in water it forms both a mono- and dihydrate, C6H4(CHO)(CH(OH)2) and C6H4(CH(OH))2O, respectively. Its reactions with nucleophiles often involves the reaction of both carbonyl groups.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
ウィキペディアで「Phthalaldehyde」の詳細全文を読む



スポンサード リンク
翻訳と辞書 : 翻訳のためのインターネットリソース

Copyright(C) kotoba.ne.jp 1997-2016. All Rights Reserved.