|
|Section2= |Section7= }} Quadricyclane is a strained, multi-cyclic hydrocarbon with potential uses as an additive for rocket propellants as well in solar energy conversion. These uses are limited, however, by the molecule's decomposition at relatively low temperatures (less than 400 °C). ==Structure and properties== Quadricyclane is a highly strained molecule (78.7 kcal/mol). Isomerization of quadricyclane proceeds slowly at low temperatures without the use of a catalyst.〔Petrov, V. A; Vasil’ev, N. V. “Synthetic Chemistry of Quadricyclane.” ''Current Organic Synthesis'' 3 (2006): 215–259〕 Because of quadricyclane’s strained structure and thermal stability, it has been studied extensively. In the presence of a catalyst norbornadiene is converted into quadricyclane via ~300nm UV radiation . When converted back to norbornadiene via irradiation, quadryicyclane’s ring strain energy is liberated in the form of heat (''ΔH'' = −89 kJ/mol). This reaction has been proposed to store solar energy.〔Dubonosov, A. D; Bren, V. A; Chernoivanov, V. A. “Norbornadiene – quadricyclane as an abiotic system for the storage of solar energy.” ''Russian Chemical Reviews'' 71 (2002): 917–927〕 However, the absorption edge of light does not extend past 300 nm whereas most solar radiation has wavelengths longer than 400 nm. Quadricyclane’s relative stability and high energy content have also given rise to its use as a propellant additive or fuel. However, quadricyclane undergoes thermal decomposition at relatively low temperatures (less than 400 °C). This property limits its applications, as propulsion systems may operate at temperatures exceeding 500 °C. 抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』 ■ウィキペディアで「Quadricyclane」の詳細全文を読む スポンサード リンク
|