|
|Section2= |Section3= }} Salcomine is a coordination complex derived from the salen ligand and cobalt. The complex, which is planar, and a variety of its derivatives are carriers for O2 as well as oxidation catalysts.〔Shoichiro Yamada “Advancement in stereochemical aspects of Schiff base metal complexes” Coordination Chemistry Reviews 1999, volume 190–192, 537–555.〕 ==Preparation and structure== The compound features square planar Co(II). It forms a variety of five-coordinate adducts, as is typical for complexes of d7 metals. In addition to oxygen and nitrogen donor sites provided by the salen2−, the metal typically is bound to pyridine (py) to give the complex Co(salen)(py). Such complexes bind O2 to give derivatives of the type (μ-O2)()2 and ().〔 Salcomine is commercially available. It may be easily synthesized from cobalt(II) acetate and salenH2: 抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』 ■ウィキペディアで「Salcomine」の詳細全文を読む スポンサード リンク
|