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Stannoxane : ウィキペディア英語版
Stannoxane
Stannoxane is a functional group in organotin chemistry with the connectivity SnIV-O-SnIV (IV indicates the oxidation state of tin). Aside from the oxide group, usually 3 or 4 other substituents are attached to tin. In aqueous or aquatic environments, most organotin compounds contain this group.〔Davies, Alwyn George. (2004) Organotin Chemistry, 2nd Edition Weinheim: Wiley-VCH. ISBN 978-3-527-31023-4〕
:
==Synthesis and formation==
Stannoxanes form upon hydrolysis of organotin halides. For example, hydrolysis of dibutyltin dichloride gives the tetratin compound 2. The hydrolysis appears to proceed via organotin hydroxides. For example, the commercially important (C6H11)3SnOH converts at 200 °C into the distannoxane:
:2 (C6H11)3SnOH → ()2O + H2O
The condensation process is proposed to occur via an associative mechanism, involving the dimer. Support for this associative mechanism is the finding that Me3SnOH exists in solution as the dimer (Me3Sn)2(μ-OH)2.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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