翻訳と辞書 Words near each other ・ Trisomy 22 ・ Trisomy 8 ・ Trisomy 9 ・ Trisong Detsen ・ Trisonic Wind Tunnel (El Segundo, California) ・ Trisophista ・ Trisops ・ Trisopterus ・ Trisopterus capelanus ・ Trisopterus esmarkii ・ Trisopterus luscus ・ Trisoxazolines ・ Trisoxazolinylborate ・ Trispectes ・ Trispectrum ・ TRISPHAT ・ Trispila ・ Trispot darter ・ Trispyrazolylborate ・ Trisquel ・ Triss ・ Trissernis ・ Trissexodon ・ Trissexodon constrictus ・ Trissexodontidae ・ Trissino ・ Trissobrocha ・ Trissochyta ・ Trissocladius ・ Trissodoris Dictionary Lists mini英和辞書 mini和英辞書 Webster 1913 Latin-English FOLDOC Wikipedia English ウィキペディア

翻訳と辞書　辞書検索 [ 開発暫定版 ] スポンサード リンク TRISPHAT ： ウィキペディア英語版 TRISPHAT |Section2= |Section3= }} Tributylammonium TRISPHAT is an organic salt with the formula ()+(). The anion features phosphorus(V) bonded to three tetrachlorocatecholate (C6Cl4O22−) ligands. This anion can be resolved into the enantiomers, which are optically stable (the picture shows the Δ enantiomer). The TRISPHAT anion has been used as a "chiral shift reagent" for cations. It improves the resolution of 1H NMR spectra by forming diastereomeric ion pairs. ==Preparation== The anion is prepared by treatment of phosphorus pentachloride with tetrachlorocatechol followed by a tertiary amine gives the anion: :PCl5 + 3 C6Cl4(OH)2 → H() + 5 HCl H() + Bu3N Bu3NH+ ()− Using a chiral amine, the anion can be readily resolved.〔F. Favarger, C. Goujon-Ginglinger, D. Monchaud, J. Lacour "Large-Scale Synthesis and Resolution of TRISPHAT (Phosphate(V) ) Anion" Journal of Organic Chemistry, 2004, volume 69, pp. 8521 -8524, 2004. .〕 抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』 ■ウィキペディアで「TRISPHAT」の詳細全文を読む スポンサード リンク 翻訳と辞書 : 翻訳のためのインターネットリソース Copyright(C) kotoba.ne.jp 1997-2016. All Rights Reserved.