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翻訳と辞書　辞書検索 [ 開発暫定版 ] スポンサード リンク Tert-Butanesulfinamide ： ウィキペディア英語版 Tert-Butanesulfinamide |Section2= }} ''tert''-Butanesulfinamide is an organosulfur compound and a member of the class of sulfinamides. Both enantiomeric forms are commercially available and are relevant to the asymmetric synthesis of amines as a chiral ammonia equivalent.〔Organic Syntheses, Vol. 82, p.157 (2005). (Link )〕 This methodology was introduced in 1997 by Jonathan A. Ellman. ==Synthesis== Chiral ''tert''-butanesulfinamide can be prepared by enantioselective oxidation of inexpensive di-''tert''-butyl disulfide to the thiosulfinate followed by disulfide bond cleavage by lithium amide. In the original scope the chiral ligand used together with vanadyl acetylacetonate was prepared by condensing a chiral aminoindanol with 3,5-di-''tert''-butyl salicylaldehyde. 抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』 ■ウィキペディアで「Tert-Butanesulfinamide」の詳細全文を読む スポンサード リンク 翻訳と辞書 : 翻訳のためのインターネットリソース Copyright(C) kotoba.ne.jp 1997-2016. All Rights Reserved.