|
Thermite is a pyrotechnic composition of metal powder fuel and metal oxide. When ignited by heat, thermite undergoes an exothermic reduction-oxidation (redox) reaction. Most varieties are not explosive but can create brief bursts of high temperature in a small area. Its form of action is similar to that of other fuel-oxidizer mixtures, such as black powder. Thermites have diverse compositions. Fuels include aluminium, magnesium, titanium, zinc, silicon, and boron. Aluminium is common because of its high boiling point and low cost. Oxidizers include bismuth(III) oxide, boron(III) oxide, silicon(IV) oxide, chromium(III) oxide, manganese(IV) oxide, iron(III) oxide, iron(II,III) oxide, copper(II) oxide, and lead(II,IV) oxide. The reaction is used for thermite welding, often used to join rail tracks. Thermites have also been used in metal refining, demolition of munitions, and in incendiary weapons. Some thermite-like mixtures are used as pyrotechnic initiators in fireworks. == Chemical reactions == In the following example, elemental aluminium reduces the oxide of another metal, in this common example iron oxide, because aluminium forms stronger, more stable, bonds with oxygen than iron: : Fe2O3 + 2 Al → 2 Fe + Al2O3 The products are aluminium oxide, elemental iron,〔(【引用サイトリンク】title=Demo Lab: The Thermite Reaction )〕 and a large amount of heat. The reactants are commonly powdered and mixed with a binder to keep the material solid and prevent separation. Other metal oxides can be used, such as chromium oxide, to generate the given metal in its elemental form. For example, a copper thermite reaction using copper oxide and elemental aluminium can be used for creating electric joints in a process called cadwelding that produces elemental copper (it may react violently): : 3 CuO + 2 Al → 3 Cu + Al2O3 Thermites with nanosized particles are described by a variety of terms, such as metastable intermolecular composites, super-thermite,〔(【引用サイトリンク】title=Low-Cost Production of Nanostructured Super-Thermites )〕 nano-thermite, and nanocomposite energetic materials.〔(【引用サイトリンク】title=Reaction Kinetics and Thermodynamics of Nanothermite Propellants )〕 抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』 ■ウィキペディアで「Thermite」の詳細全文を読む スポンサード リンク
|