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Thiocyanatoiron : ウィキペディア英語版 | Thiocyanatoiron
Thiocyanatoiron (systematically named thiocyanatoiron(2+)) is a inorganic cation with the chemical formula ()2+. It is known to produce a blood red color in solution. This is used as a test for Fe3+ in the laboratory. Fe3+ reacts with thiocyanate to give a series of intensely red colored compounds which remain in the solution and does not undergo any reaction after the formation of the stable octahedral structure. In high concentration of SCN− the compound is fairly octahedral with six thiocyanate ligands bonded to iron atom. Thiocyanatoiron forms a pentahydrate. Thiocyanatoiron must be stored in an acidic solution to prevent the formation of FeOH2+ ions. The excess H+ ions in the acidic solution prevent Fe3+ from engaging in side reactions. Thiocyanatoiron decomposes with exposure to light. The thiocyanatoiron ion is usually formed through an equilibrium reaction: :Fe3+(aq) + SCN−(aq) ↔ ()2+(aq) == Chemical properties ==
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