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・ Thiocolchicoside
・ Thiocyanate
・ Thiocyanate hydrolase
・ Thiocyanate isomerase
・ Thiocyanatoiron
・ Thiocyanic acid
・ Thiocyanogen
・ Thiodia
・ Thiodia citrana
・ Thiodia glandulosana
・ Thiodia lerneana
・ Thiodia torridana
・ Thiodiglycol
・ Thiodina
・ Thiodiodes
Thioenol
・ Thioescaline
・ Thioester
・ Thioester-containing protein 1
・ Thioesterase
・ Thioethanolamine S-acetyltransferase
・ Thioether
・ Thioether S-methyltransferase
・ Thiofanox
・ Thiofentanyl
・ Thioflavin
・ Thiofrid of Echternach
・ Thioglycolate broth
・ Thioglycolic acid
・ Thiognatha


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Thioenol : ウィキペディア英語版
Thioenol
Thioenols (also known as alkenthiols) are alkenes with a thiol group affixed to one of the carbon atoms composing the double bond. Alkenes with a thiol group on both sides of the double bond are called enedithiols. Deprotonated anions of thioenols are called thioenolates.
The C=C double bond with adjacent thiol gives thioenols and enedithiols their chemical characteristics, by which they present keto-enol tautomerism. In keto-enol tautomerism, thioenols interconvert with thioketones or thioaldehydes.
The words thioenol and alkenthiol come from the words "alkene" (or just -ene, the suffix given to C=C double bonded alkenes) and "thiol" (which represents the thioenol's thiol group).
== Thioketo-thioenol tautomerism ==

Thioenols interconvert with thiocarbonyl compounds that have an α-hydrogen, like thioketones and thioaldehydes. The compound is deprotonated on one side and protonated on another side, whereas a single bond and a double bond are exchanged. This is called keto-enol tautomerism.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
ウィキペディアで「Thioenol」の詳細全文を読む



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