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・ Thioether
・ Thioether S-methyltransferase
・ Thiofanox
・ Thiofentanyl
・ Thioflavin
・ Thiofrid of Echternach
・ Thioglycolate broth
・ Thioglycolic acid
・ Thiognatha
・ Thiognatha mameti
・ Thiognatha metachalca
・ Thioindigo
・ Thioinosinic acid
・ Thioketal
・ Thioketene
Thioketone
・ Thiokinase
・ Thiokol
・ Thiokol (polymer)
・ Thiokol-Woodbine explosion
・ Thiol
・ Thiol oxidase
・ Thiol S-methyltransferase
・ Thiol sulfotransferase
・ Thiol-activated cytolysin
・ Thiol-ene reaction
・ Thiol-yne reaction
・ Thiolactic acid
・ Thiolactone
・ Thiolase


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Thioketone : ウィキペディア英語版
Thioketone

Thioketones (also known as thiones or thiocarbonyls) are organosulfur compounds related to conventional ketones. Instead of the formula R2C=O, thioketones have the formula R2C=S, which is reflected by the prefix "thio-" in the name of the functional group. Unhindered alkylthioketones typically tend to form polymers or rings.
==Preparative methods==
Thiones are usually prepared from ketones using reagents that exchange S and O atoms. A common reagent is phosphorus pentasulfide〔Vivek Polshettiwar, M.P. Kaushik "A new, efficient and simple method for the thionation of ketones to thioketones using P4S10/Al2O3" Tetrahedron Letters 2004, Volume 45, 6255-6257. 〕 and its derivative Lawesson's reagent. Other methods uses a mixture of hydrogen chloride combined with hydrogen sulfide. Bis(trimethylsilyl)sulfide has also been employed.

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