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Thioketone
Thioketones (also known as thiones or thiocarbonyls) are organosulfur compounds related to conventional ketones. Instead of the formula R2C=O, thioketones have the formula R2C=S, which is reflected by the prefix "thio-" in the name of the functional group. Unhindered alkylthioketones typically tend to form polymers or rings. ==Preparative methods== Thiones are usually prepared from ketones using reagents that exchange S and O atoms. A common reagent is phosphorus pentasulfide〔Vivek Polshettiwar, M.P. Kaushik "A new, efficient and simple method for the thionation of ketones to thioketones using P4S10/Al2O3" Tetrahedron Letters 2004, Volume 45, 6255-6257. 〕 and its derivative Lawesson's reagent. Other methods uses a mixture of hydrogen chloride combined with hydrogen sulfide. Bis(trimethylsilyl)sulfide has also been employed.
抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)』 ■ウィキペディアで「Thioketone」の詳細全文を読む
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