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翻訳と辞書　辞書検索 [ 開発暫定版 ] スポンサード リンク Tricyclohexylphosphine ： ウィキペディア英語版 Tricyclohexylphosphine |Section2= |Section3= }} Tricyclohexylphosphine is the tertiary phosphine with the formula P(C6H11)3. Commonly used as a ligand in organometallic chemistry, it is often abbreviated to PCy3, where Cy stands for cyclohexyl. It is characterized by both high basicity (pKa = 9.7)〔C. A. Streuli, "Determination of Basicity of Substituted Phosphines by Nonaqueous Titrimetry", Analytical Chemistry 1960, volume 32, pages 985-987.〕 and a large ligand cone angle (170°). Important complexes containing P(Cy)3 ligands include the 2005 Nobel Prize-winning Grubbs' catalyst and the homogeneous hydrogenation catalyst Crabtree's catalyst. ==References== 〔 Image:Grubbs_Catalyst_1st_Generation.svg|Grubbs catalyst (1st generation) Image:Crabtree.png|Crabtree's catalyst 抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』 ■ウィキペディアで「Tricyclohexylphosphine」の詳細全文を読む スポンサード リンク 翻訳と辞書 : 翻訳のためのインターネットリソース Copyright(C) kotoba.ne.jp 1997-2016. All Rights Reserved.