翻訳と辞書 Words near each other ・ Trifurcula macedonica ・ Trifurcula magna ・ Trifurcula manygoza ・ Trifluoromethanesulfonic acid ・ Trifluoromethanesulfonic anhydride ・ Trifluoromethanesulfonyl azide ・ Trifluoromethyl ・ Trifluoromethyl hypofluorite ・ Trifluoromethyl sulphur pentafluoride ・ Trifluoromethylaminoindane ・ Trifluoromethylation ・ Trifluoromethylisocyanide ・ Trifluoromethylphenylpiperazine ・ Trifluoromethylsulfonyl ・ Trifluoromethyltrimethylsilane ・ Trifluorooxonium ・ Trifluorotoluene ・ Trifluperidol ・ Triflupromazine ・ Trifluralin ・ Trifluridine ・ Trifluridine/tipiracil ・ Triflusal ・ Trifocal ・ Trifocal lenses ・ Trifocal tensor ・ Trifoliate orange ・ Trifolieae ・ Trifolin ・ Trifolium albopurpureum Dictionary Lists mini英和辞書 mini和英辞書 Webster 1913 Latin-English FOLDOC Wikipedia English ウィキペディア

翻訳と辞書　辞書検索 [ 開発暫定版 ] スポンサード リンク Trifluorooxonium ： ウィキペディア英語版 Trifluorooxonium The trifluorooxonium cation is a hypothetical positively charged polyatomic ion with chemical formula . It is structurally equivalent to the hydronium ion where the hydrogen atoms surrounding the central oxygen atom have been replaced by fluorine, and is isoelectronic with nitrogen trifluoride. This cation would be an example of oxygen in the +4 oxidation state. The cation was shown to be vibrationally stable at all levels of theory applied (HF, MP2, CCSD(T)). was proposed to possess a pyramidal structure with an O–F bond length of 1.395 Å and F–O–F bond angles of 104.2° (CCSD(T) level of theory). The detachment energy of the cation was calculated to be +110.1 kcalmol−1. However, the low-temperature reaction of , and under UV irradiation, besides unreacted starting materials only yielded the dioxygenyl salt . The oxidation of with salts also failed to produce evidence for the title cation. The formation of the hypothetical salt was calculated to be about thermoneutral, but slightly unfavorable with (g) + (g) + (g) → (s) = +10.5 kcalmol−1. ==See also== *Tetrafluoroammonium 抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』 ■ウィキペディアで「Trifluorooxonium」の詳細全文を読む スポンサード リンク 翻訳と辞書 : 翻訳のためのインターネットリソース Copyright(C) kotoba.ne.jp 1997-2016. All Rights Reserved.