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Trimerization : ウィキペディア英語版
Trimer (chemistry)

In chemistry, a trimer () (''tri-'', "three" + ''-mer'', "parts") is an oligomer derived from three identical precursors. An example is the procedure of production of polymers. At first, a monomer is made. By combining two monomers, a dimer is produced. With further additions, a trimer and eventually a polymer is made. Often, trimerization competes with polymerization; for example, dimethylsilanediol polymerizes to polydimethylsiloxane, even though a trimer is made:
: Me2Si(OH)2 + (HO)2SiMe2 → Me2(OH)Si-O-Si(OH)Me2 – ''dimer''
: Me2(OH)Si-O-Si(OH)Me2 + (HO)2SiMe2 → Me2(OH)Si-O-SiMe2-O-Si(OH)Me2 – ''trimer''
: Me2(OH)Si-O-SiMe2-O-Si(OH)Me2 + (HO)2SiMe2 → Me2(OH)Si-O-SiMe2-O-SiMe2-O-Si(OH)Me2 – ''tetramer''
: et cetera, until Me2(OH)Si-O-()nSi(OH)Me2 (n>100) – ''polymer''
Trimers are typically cyclic. Chemical compounds that often trimerise are aliphatic isocyanates and cyanic acids.
==Trimerisation via breaking triple bond==


抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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