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|Section2= |Section7= |Section8= }} Trimethylolethane (TME) is the organic compound with the formula CH3C(CH2OH)3. This colorless solid is a triol, that is it contains three hydroxy functional groups. More specifically, it features three primary alcohol groups in a compact neopentyl structure. Its esters are known for their resistance to heat, light, hydrolysis, and oxidation. More important than TME and closely related is trimethylolpropane (TMP). ==Production== Trimethylolethane is produced via a two step process, starting with the condensation reaction of propionaldehyde with formaldehyde: :CH3CH2CHO + 2 CH2O → CH3C(CH2OH)2CHO The second step entails a Cannizaro reaction: :CH3C(CH2OH)2CHO + CH2O + NaOH → CH3C(CH2OH)3 + NaO2CH A few thousand tons are produced annually in this way.〔Peter Werle, Marcus Morawietz, Stefan Lundmark, Kent Sörensen, Esko Karvinen, Juha Lehtonen “Alcohols, Polyhydric” in Ullmann’s Encyclopedia of Industrial Chemistry, Wiley-VCH, Weinheim, 2008.〕 抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)』 ■ウィキペディアで「Trimethylolethane」の詳細全文を読む スポンサード リンク
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