翻訳と辞書
Words near each other
・ Tripfall
・ Tripflare
・ Tripfordine
・ Triphaenopsis
・ Triphaenopsis jezoensis
・ Triphala
・ Triphalangeal thumb
・ Triphasia
・ Triphasia brassii
・ Triphasia grandifolia
・ Triphasia trifolia
・ Triphassa
・ Triphenyl phosphate
・ Triphenyl phosphite
・ Triphenylamine
Triphenylarsine
・ Triphenylborane
・ Triphenylcarbethoxymethylenephosphorane
・ Triphenylcyclopropenium bromide
・ Triphenylene
・ Triphenylmethane
・ Triphenylmethanol
・ Triphenylmethyl chloride
・ Triphenylmethyl hexafluorophosphate
・ Triphenylmethyl radical
・ Triphenylphosphine
・ Triphenylphosphine dichloride
・ Triphenylphosphine oxide
・ Triphenylphosphine selenide
・ Triphenylphosphine sulfide


Dictionary Lists
翻訳と辞書 辞書検索 [ 開発暫定版 ]
スポンサード リンク

Triphenylarsine : ウィキペディア英語版
Triphenylarsine

|Section2=
|Section3=
|Section4=
|Section5=
}}
Triphenylarsine is the chemical compound with the formula As(C6H5)3. This organoarsenic compound, often abbreviated AsPh3, is a colorless crystalline solid that is used as a ligand and a reagent in coordination chemistry and organic synthesis. The molecule is pyramidal with As-C distances of 1.942–1.956 Å and C-As-C angles of 99.6–100.5°.〔Mazhar-ul-Haque, Hasan A. Tayim, Jamil Ahmed, and William Horne "Crystal and molecular structure of triphenylarsine" ''Journal of Chemical Crystallography'' Volume 15, Number 6 / 1985. 〕
This compound is prepared by the reaction of arsenic trichloride with chlorobenzene using sodium as the reducing agent:〔 (article )〕
:AsCl3 + 3 PhCl + 6 Na → AsPh3 + 6 NaCl
==Uses==
AsPh3 is the precursor to tetraphenylarsonium chloride, ()Cl, a popular precipitating agent.〔
AsPh3 forms complexes with low valent metals that are analogous to the corresponding triphenylphosphine derivatives, such as IrCl(CO)(AsPh3)2 and RhCl(AsPh3)3.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
ウィキペディアで「Triphenylarsine」の詳細全文を読む



スポンサード リンク
翻訳と辞書 : 翻訳のためのインターネットリソース

Copyright(C) kotoba.ne.jp 1997-2016. All Rights Reserved.