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Triphenylphosphine
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Triphenylphosphine : ウィキペディア英語版
Triphenylphosphine

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Triphenylphosphine (IUPAC name: triphenylphosphane) is a common organophosphorus compound with the formula P(C6H5)3 - often abbreviated to PPh3 or Ph3P. It is widely used in the synthesis of organic and organometallic compounds. PPh3 exists as relatively air stable, colorless crystals at room temperature. It dissolves in non-polar organic solvents such as benzene and diethyl ether.
==Preparation, structure, handling==
Triphenylphosphine is a relatively inexpensive substance. It can be prepared in the laboratory by treatment of phosphorus trichloride with phenylmagnesium bromide or phenyllithium. The industrial synthesis involves the reaction between phosphorus trichloride, chlorobenzene, and sodium.:
::PCl3 + 3PhCl + 6Na → PPh3 + 6NaCl

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