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・ Triphenylsulfonium triflate
・ Triphenyltin chloride
・ Triphenyltin compounds
・ Triphenyltin hydride
・ Triphenyltin hydroxide
・ Triphon Silyanovski
・ Triphone
・ Triphora
・ Triphora (gastropod)
・ Triphora (orchid)
・ Triphora trianthophora
・ Triphoreae
・ Triphoridae
・ Triphorinae
・ Triphoroidea
Triphos
・ Triphosa
・ Triphosa dubitata
・ Triphosa rantaizanensis
・ Triphosa sabaudiata
・ Triphosgene
・ Triphosphane
・ Triphosphatase
・ Triphosphate—protein phosphotransferase
・ Triphosphoribosyl-dephospho-CoA synthase
・ Triphosphoric acid
・ Triphosphorus pentanitride
・ Triphoturus
・ Triphthong
・ Triphylia


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Triphos : ウィキペディア英語版
Triphos

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Triphos is the name for certain organophorus ligands. They are air-sensitive white solids that function as tridentate ligands in coordination and organometallic chemistry.
==Bis(diphenylphosphinoethyl)phenylphosphine==
Bis(diphenylphosphinoethyl)phenylphosphine is called triphos, is a linear tridentate triphosphine. It is prepared by the free-radical-catalysed addition of phenylphosphine to vinyldiphenylphosphine:〔"Synthesis of Polytertiary Phosphines and ‘Mixed’ Phosphorus–Sulphur and ‘Mixed’ Phosphorus–Nitrogen Polydentate Ligands via Free-Radical Catalysis" Daniel L. DuBois, William H. Myers and Devon W. Meek J. Chem. Soc., Dalton Trans., 1975, 1011-1015.〕
:2 Ph2PCH=CH2 + H2PPh → ()2PPh
This isomer of triphos is flexible and can bind to an octahedral metal center give either a facial or meridional isomers. Some derivatives are square planar complexes of the type ()+ (M = Ni, Pd, Pt; X = halide).

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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