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・ Triruthenium dodecacarbonyl
・ Tris
・ Tris (disambiguation)
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・ Tris(1,3-dichloro-2-propyl)phosphate
・ Tris(2,3-dibromopropyl) phosphate
・ Tris(2-aminoethyl)amine
・ Tris(2-chloroethyl) phosphate
Tris(2-pyridylmethyl)amine
・ Tris(8-hydroxyquinolinato)aluminium
・ Tris(acetonitrile)cyclopentadienylruthenium hexafluorophosphate
・ Tris(acetylacetonato)iron(III)
・ Tris(benzyltriazolylmethyl)amine
・ Tris(bipyridine)ruthenium(II) chloride
・ Tris(dibenzylideneacetone)dipalladium(0)
・ Tris(dimethylamino)aluminium dimer
・ Tris(dimethylamino)gallium dimer
・ Tris(ethylenediamine)cobalt(III) chloride
・ Tris(pentafluorophenyl)borane
・ Tris(tert-butoxy)silanethiol
・ Tris(triphenylphosphine)rhodium carbonyl hydride
・ Tris-buffered saline
・ Trisaccharide


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Tris(2-pyridylmethyl)amine : ウィキペディア英語版
Tris(2-pyridylmethyl)amine

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Tris(2-pyridylmethyl)amine (abbreviated TPMA or TPA) is an organic compound with the formula (C5H4NCH2)3N. It is a tertiary amine with three picolyl substituents. It is a white solid that is soluble in polar organic solvents. It is a ligand in coordination chemistry.
The ligand is prepared by the alkylation of picolylamine by picolyl chloride:
:2 C5H4NCH2Cl + C5H4NCH2NH2 → (C5H4NCH2)3N + 2 HCl
TPA is a tripodal ligand, often used to simulate the coordination environment within some proteins. It is also used as a copper ligand in ATRP. A related ligand is dipicolylamine, which in fact is an intermediate in the synthesis of TPA.
==References==


抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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