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・ Vanadium tetrafluoride
・ Vanadium(II) bromide
・ Vanadium(II) chloride
・ Vanadium(II) oxide
・ Vanadium(III) bromide
・ Vanadium(III) chloride
・ Vanadium(III) fluoride
・ Vanadium(III) iodide
・ Vanadium(III) oxide
・ Vanadium(III) sulfate
・ Vanadium(IV) oxide
・ Vanadium(V) oxide
・ Vanadium(V) oxytrifluoride
・ Vanadium-gallium
・ Vanadjou
Vanadocene
・ Vanadocene dichloride
・ Vanadurga
・ Vanadurga Fort
・ Vanadyl acetylacetonate
・ Vanadyl ion
・ Vanadyl nitrate
・ Vanadyl perchlorate
・ Vanadyl sulfate
・ Vanadzor
・ Vanadzor River
・ Vanadzor State University
・ Vanagaram
・ Vanags
・ Vanahalli


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Vanadocene : ウィキペディア英語版
Vanadocene

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Vanadocene, bis(η5-cyclopentadienyl) vanadium, is the organometallic compound with the formula V(C5H5)2, commonly abbreviated Cp2V. It is a violet crystalline, paramagnetic solid. Vanadocene has relatively limited practical use, but it has been extensively studied.
== Structure and bonding ==
V(C5H5)2 is a metallocene, a class of organometallic compounds that typically have a metal ion sandwiched between two cyclopentadienyl rings. In the solid state, the molecule has D5d symmetry. The vanadium(II) center resides equidistant between the center of the two cyclopentadienyl rings at a crystallographic center of inversion. The average V-C bond distance is 226 pm. The Cp rings of vanadocene are dynamically disordered at temperatures above 170 K and are only fully ordered at 108 K.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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