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Wurtzite : ウィキペディア英語版
Wurtzite

:''This article is about the mineral wurtzite. For the wurtzite crystal structure, see Wurtzite (crystal structure).''
Wurtzite is a zinc iron sulfide mineral ((Zn,Fe)S) a less frequently encountered mineral form of sphalerite. The iron content is variable up to eight percent.〔Palache, Charles, Harry Berman & Clifford Frondel (1944), ''The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana,'' Yale University 1837-1892, Volume I: Elements, Sulfides, Sulfosalts, Oxides. John Wiley and Sons, Inc., New York. 7th edition, revised and enlarged, pp. 226-228.〕 It is trimorphous with matraite and sphalerite.〔
It occurs in hydrothermal deposits associated with sphalerite, pyrite, chalcopyrite, barite and marcasite. It also occurs in low-temperature clay-ironstone concretions.〔
It was first described in 1861 for an occurrence in the San José Mine, Oruro City, Cercado Province, Oruro Department, Bolivia, and named for French chemist Charles-Adolphe Wurtz.〔 It has widespread distribution. In Europe it is reported from Příbram, Czech Republic; Hesse, Germany; and Liskeard, Cornwall, England. In the US it is reported from Litchfield County, Connecticut; Butte, Silver Bow County, Montana; at Frisco, Beaver County, Utah; and from the Joplin district, Jasper County, Missouri.〔
==Wurtzite structure==

The wurtzite group includes: Cadmoselite CdSe, Greenockite CdS, Mátraite ZnS and Rambergite MnS, in addition to wurtzite.〔(Wurtzite at Mindat.org )〕
Its crystal structure is called the wurtzite crystal structure, to which it lends its name. This structure is a member of the hexagonal crystal system and consists of tetrahedrally coordinated zinc and sulfur atoms that are stacked in an ABABABABAB pattern.
The unit cell parameters of wurtzite are (-2H polytype):〔
*''a'' = ''b'' = 3.82 Å = 382 pm
*''c'' = 6.26 Å = 626 pm
*V = 79.11 Å3
*Z = 2

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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