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aerographite : ウィキペディア英語版 | aerographite
Aerographite is a synthetic foam consisting of a porous interconnected network of tubular carbon. With a density of 180 g/m3 it is one of the lightest structural materials ever created. It was developed jointly by a team of researchers at the University of Kiel and the Technical University of Hamburg in Germany, and was first reported in a scientific journal in June 2012. ==Structure and properties== Aerographite is a black freestanding material that can be produced in various shapes occupying a volume of up to several cubic centimeters. It consists of a seamless interconnected network of carbon tubes that have micron-scale diameters and a wall thickness of about 15 nm. Because of the relatively lower curvature and larger wall thickness, these walls differ from the graphene-like shells of carbon nanotubes and resemble vitreous carbon in their properties. These walls are often discontinuous and contain wrinkled areas that improve the elastic properties of aerographite. The carbon bonding in aerographite has an sp2 character, as confirmed by electron energy loss spectroscopy and electrical conductivity measurements. Upon external compression, the conductivity increases, along with material density, from ~0.2 S/m at 0.18 mg/cm3 to 0.8 S/m at 0.2 mg/cm3. The conductivity is higher for a denser material, 37 S/m at 50 mg/cm3.〔 Owing to its interconnected tubular network structure, aerographite resists tensile forces much better than other carbon foams as well as silica aerogels. It sustains extensive elastic deformations and has a very low Poisson's ratio. A complete shape recovery of a 3-mm-tall sample after it was compressed down to 0.1 mm is possible. Its ultimate tensile strength (UTS) depends on material density and is about 160 kPa at 8.5 mg/cm3 and 1 kPa at 0.18 mg/cm3; in comparison, the strongest silica aerogels have a UTS of 16 kPa at 100 mg/cm3. The Young's modulus is ca. 15 kPa at 0.2 mg/cm3 in tension, but is much lower in compression, increasing from 1 kPa at 0.2 mg/cm3 to 7 kPa at 15 mg/cm3.〔 The density given by the authors is based a mass measurement and the determination of the outer volume of the synthetic foams as usually performed also for other structures. Aerographite is superhydrophobic, thus its centimeter-sized samples repel water; they are also rather sensitive to electrostatic effects and spontaneously jump to charged objects.〔
抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)』 ■ウィキペディアで「aerographite」の詳細全文を読む
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