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benzotriazole : ウィキペディア英語版
benzotriazole

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Benzotriazole (BTA) is a heterocyclic compound containing three nitrogen atoms, with the chemical formula C6H5N3. This aromatic compound is colorless and polar and can be used in various fields.
== Structure ==
Benzotriazole features two fused rings. Its five-membered ring can exist in tautomers A and B, and the derivatives of both tautomers, structures C and D also can be produced.

Various structural analyses with UV, IR and 1H-NMR spectra indicated that isomer A is predominantly present at room temperature. The bond between positions 1 and 2 and the one between positions 2 and 3 have proved to have the same bond properties. Moreover, the proton does not tightly bind to any of the nitrogen atoms, but rather migrates rapidly between positions 1 and 3. Therefore, the BTA can lose a proton to act as a weak acid (pKa = 8.2)〔〔 or accept a proton using the lone pair electrons located on its nitrogen atoms as a very weak Bronsted base (pKa < 0).〔 Not only can it act either as an acid or base, it can also bind to other species, utilizing the lone pair electrons. Applying this property, the BTA can form a stable coordination compound on a copper surface and behave as a corrosion inhibitor.〔

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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