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bifluoride : ウィキペディア英語版
bifluoride

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Bifluoride is an inorganic anion with the chemical formula HF (also written ()). It contributes no color to bifluoride salts. Salts of bifluoride are used to etch glass.
==Acid-base properties and production==
Bifluoride undergoes the typical chemical reactions of a weak acid. Upon treatment with a standard acid, it converts to hydrofluoric acid and a metal salt. Oxidation of bifluoride gives fluorine. When heated, bifluoride salts decompose to produce fluoride salts and hydrogen fluoride:
:() HF + F
Bifluoride protonates to give hydrogen fluoride:
:HF + H+ 2 HF
Because of this capture of a proton (H+), bifluoride has basic character. Its conjugate acid is the reactive intermediate, μ-fluoro-fluorodihydrogen (H2F2), which subsequently dissociates to become hydrogen fluoride. In solution, most bifluoride ions are dissociated.
: + 2 HF +
Bifluoride salts arise by treatment of hydrogen fluoride with base:
:HF + F → ()

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