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borazine : ウィキペディア英語版
borazine

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Borazine is an inorganic compound with the chemical formula (BH)3(NH)3. In this cyclic compound, the three BH units and three NH units alternate. The compound is isoelectronic and isostructural with benzene. Like benzene, borazine is a colourless liquid. For this reason borazine is sometimes referred to as "inorganic benzene".
== Synthesis ==
The compound was reported in 1926 by the chemists Alfred Stock and Erich Pohland by a reaction of diborane with ammonia.
Borazine is synthesized from diborane and ammonia in a 1:2 ratio at 250–300 °C with a conversion of 50%.
:3 B2H6 + 6 NH3 → 2 B3H6N3 + 12 H2
An alternative more efficient route begins with lithium borohydride and ammonium chloride:
:3 LiBH4 + 3 NH4Cl → B3H6N3 + 3 LiCl + 9 H2
In a two-step process to borazine, boron trichloride is first converted to trichloroborazine:
:3 BCl3 + 3 NH4Cl → Cl3B3H3N3 + 9 HCl
The B-Cl bonds are subsequently converted to B-H bonds:
:2 Cl3B3H3N3 + 6 NaBH4 → 2 B3H6N3 + 3 B2H6 + 6 NaCl

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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