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cobalt : ウィキペディア英語版
cobalt

Cobalt is a chemical element with symbol Co and atomic number 27. Like nickel, cobalt in the Earth's crust is found only in chemically combined form, save for small deposits found in alloys of natural meteoric iron. The free element, produced by reductive smelting, is a hard, lustrous, silver-gray metal.
Cobalt-based blue pigments (cobalt blue) have been used since ancient times for jewelry and paints, and to impart a distinctive blue tint to glass, but the color was later thought by alchemists to be due to the known metal bismuth. Miners had long used the name ''kobold ore'' (German for ''goblin ore'') for some of the blue-pigment producing minerals; they were so named because they were poor in known metals, and gave poisonous arsenic-containing fumes upon smelting. In 1735, such ores were found to be reducible to a new metal (the first discovered since ancient times), and this was ultimately named for the ''kobold''.
Today, some cobalt is produced specifically from various metallic-lustered ores, for example cobaltite (CoAsS), but the main source of the element is as a by-product of copper and nickel mining. The copper belt in the Democratic Republic of the Congo and Zambia yields most of the cobalt mined worldwide.
Cobalt is primarily used as the metal, in the preparation of magnetic, wear-resistant and high-strength alloys. Its compounds cobalt silicate and cobalt(II) aluminate (CoAl2O4, cobalt blue) give a distinctive deep blue color to glass, ceramics, inks, paints and varnishes. Cobalt occurs naturally as only one stable isotope, cobalt-59. Cobalt-60 is a commercially important radioisotope, used as a radioactive tracer and for the production of high energy gamma rays.
Cobalt is the active center of coenzymes called cobalamins, the most common example of which is . As such it is an essential trace dietary mineral for all animals. Cobalt in inorganic form is also an active nutrient for bacteria, algae and fungi.
==Characteristics==

Cobalt is a ferromagnetic metal with a specific gravity of 8.9. The Curie temperature is and the magnetic moment is 1.6–1.7 Bohr magnetons per atom. Cobalt has a relative permeability two-thirds that of iron. Metallic cobalt occurs as two crystallographic structures: hcp and fcc. The ideal transition temperature between the hcp and fcc structures is , but in practice, the energy difference is so small that random intergrowth of the two is common.〔(【引用サイトリンク】Properties and Facts for Cobalt )
Cobalt is a weakly reducing metal that is protected from oxidation by a passivating oxide film. It is attacked by halogens and sulfur. Heating in oxygen produces Co3O4 which loses oxygen at to give the monoxide CoO.〔 The metal reacts with fluorine (F2) at 520 K to give CoF3; with chlorine (Cl2), bromine (Br2) and iodine (I2), the corresponding binary halides are formed. It does not react with hydrogen gas (H2) or nitrogen gas (N2) even when heated, but it does react with boron, carbon, phosphorus, arsenic and sulfur. At ordinary temperatures, it reacts slowly with mineral acids, and very slowly with moist, but not with dry, air.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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