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cuneane : ウィキペディア英語版
cuneane

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Cuneane (C8H8, Pentacyclo(2,4.03,7.06,8 )octane) is a saturated hydrocarbon.〔with 3D-structure (however molecular graph of cuneane is a planar graph)〕 Its name is derived from the Latin “cuneus”, meaning a wedge. Cuneane may be produced from cubane by metal-ion-catalyzed σ-bond rearrangement. Similar reactions are known for homocubane (C9H10) and bishomocubane (C10H10).
:
The cuneane molecule has three groups of equivalent carbon atoms (A, B, C), which have also been confirmed by NMR. The molecular graph of the carbon skeleton of cuneane is a regular graph with non-equivalent groups of vertices, and so it is a very important test object for different algorithms of mathematical chemistry.

:
Some cuneane derivatives have liquid crystal properties.
==External links==

* 2D and 3D Models of Dodecahedrane and Cuneane Assemblies (Link )

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
ウィキペディアで「cuneane」の詳細全文を読む



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