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Cyanopolyynes are a group of chemicals with the chemical formula (n=3,5,7, ...). Structurally, they are acetylene groups covalently bonded in a string with a cyano group attached at the end. A rarely seen group of molecules both due to the difficulty in production and the unstable nature of the paired groups, the cyanopolyynes have been observed as a major organic component in interstellar clouds.〔Turner, B. E. (1971). DETECTION OF INTERSTELLAR CYANOACETYLENE. Astrophysical Journal, 163(1), L35-&. doi: 10.1086/180662〕 This is believed to be due to the hydrogen scarcity of some of these clouds. Interference with hydrogen is one of the reason for the molecule's instability due to the energetically favorable dissociation back into hydrogen cyanide and acetylene.〔Balucani, N., Asvany, O., Huang, L. C. L., Lee, Y. T., Kaiser, R. I., Osamura, Y., & Bettinger, H. F. (2000). Formation of nitriles in the interstellar medium via reactions of cyano radicals, CN(X (2)Sigma(+)), with unsaturated hydrocarbons. Astrophysical Journal, 545(2), 892-906. 〕 Cyanopolyynes were first discovered in interstellar molecular clouds in 1971 using millimeter wave and microwave telescopes.〔 Since then many higher weight cyanopolyynes such as and have been discovered, although some of these identifications have been disputed. Other derivatives such as methycyanoacetylene and ethylcyanoacetylene have been observed as well.〔Broten, N. W., Macleod, J. M., Avery, L. W., Irvine, W. M., Hoglund, B., Friberg, P., & Hjalmarson, A. (1984). THE DETECTION OF INTERSTELLAR METHYLCYANOACETYLENE. Astrophysical Journal, 276(1), L25-L29. 〕 The simplest example is cyanoacetylene, H−C≡C−C≡N. Cyanoacetylene is more common on earth and it is believed to be the initial reagent for most of the photo-catalyzed formation of the interstellar cyanopolyynes. Cyanoacetylene is one of the molecules that was produced in the Miller–Urey experiment and is expected to be found in carbon-rich environments.〔McCollom, T. M. (2013). Miller-Urey and Beyond: What Have We Learned About Prebiotic Organic Synthesis Reactions in the Past 60 Years? In R. Jeanloz (Ed.), Annual Review of Earth and Planetary Sciences, Vol 41 (Vol. 41, pp. 207-229). Palo Alto: Annual Reviews.〕 Identification is made through comparison of experimental spectrum with spectrum gathered from the telescope. This is commonly done with measurement of the rotational constant, the energy of the rotational transitions, or a measurement of the dissociation energy. These spectra can either be generated ab initio from a computational chemistry program or, such as with the more stable cyanoacetylene, by direct measurement of the spectra in an experiment. Once the spectra are generated, the telescope can scan within certain frequencies for the desired molecules. Quantification can be accomplished as well to determine the density of the compounds in the cloud. ==Hypothesized formation of cyanopolyynes== The formation of cyanopolyynes in interstellar clouds is time-dependent. The formation of cyanopolyyne was studied and the abundances calculated in the dark cloud, TMC-1. In the early days of the universe, the governing reactions were ion-molecule reactions. During this time cyanoacetylene, HC3N, formed through a series of ion-neutral reactions, with the final chemical reaction being: C3H2 + N→HC3N+H However, for time after 10,000 years the dominant reactions were neutral-neutral reactions and two reaction mechanisms for the formation of cyanopolyynes became possible. (1) 抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』 ■ウィキペディアで「cyanopolyyne」の詳細全文を読む スポンサード リンク
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