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cyclohexanol : ウィキペディア英語版
cyclohexanol

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Cyclohexanol is the organic compound with the formula (CH2)5CHOH. The molecule is related to cyclohexane ring by replacement of one hydrogen atom by a hydroxyl group. This compound exists as a deliquescent colorless solid with a camphor-like odor, which, when very pure, melts near room temperature. Billions of kilograms are produced annually, mainly as a precursor to nylon.〔Michael Tuttle Musser "Cyclohexanol and Cyclohexanone" in Ullmann's Encyclopedia of Industrial Chemistry, Wiley-VCH, Weinheim, 2005.〕
==Production==
Cyclohexanol is produced by the oxidation of cyclohexane in air, typically using cobalt catalysts:〔
:C6H12 + 1/2 O2 → C6H11OH
This process co-forms cyclohexanone, and this mixture ("KA oil" for ketone-alcohol oil) is the main feedstock for the production of adipic acid. The oxidation involves radicals and the intermediacy of the hydroperoxide C6H11O2H.
Alternatively, cyclohexanol can be produced by the hydrogenation of phenol:
:C6H5OH + 3 H2 → C6H11OH
This process can also be adjusted to favor the formation of cyclohexanone.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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