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diazirine : ウィキペディア英語版
diazirine

Diazirines are a class of organic molecules consisting of a carbon bound to two nitrogen atoms, which are double-bonded to each other, forming a cyclopropene-like ring. They are mainly used as carbene precursor and also in photoaffinity labelling studies of nucleic acids and proteins.〔Photoactivatable Reagents Based on Aryl(trifluoromethyl)diazirines: Synthesis and Application for Studying Nucleic Acid–Protein Interactions; G. A. Korshunova, N. V. Sumbatyan, A. N. Topin, and M. T. Mtchedlidze, ''Molecular Biology'', 2000, ''34'', 823-839. 〕
==Reactions==
:
Diazirines are unstable in the presence of light, decaying upon photolysis to form the corresponding carbene and nitrogen gas. This reaction can also be performed thermally.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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