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翻訳と辞書　辞書検索 [ 開発暫定版 ] スポンサード リンク dichlorocarbene ： ウィキペディア英語版 dichlorocarbene |Section2= |Section3= }} Dichlorocarbene is the reactive intermediate with chemical formula CCl2. Although this material has not been isolated, it is a common intermediate in organic chemistry, being generated from chloroform. This bent diamagnetic molecule rapidly inserts into other bonds. ==Preparation== Dichlorocarbene is most commonly generated by reaction of chloroform and a base such as potassium ''t''-butoxide or aqueous sodium hydroxide.〔Organic Syntheses, Coll. Vol. 5, p.874 (1973); Vol. 41, p.76 (1961).()〕 A phase transfer catalyst, for instance benzyltriethylammonium bromide, facilitates the migration of the hydroxide in the organic phase. :HCCl3 + NaOH → CCl2 + NaCl + H2O 抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』 ■ウィキペディアで「dichlorocarbene」の詳細全文を読む スポンサード リンク 翻訳と辞書 : 翻訳のためのインターネットリソース Copyright(C) kotoba.ne.jp 1997-2016. All Rights Reserved.