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dimethylzinc : ウィキペディア英語版
dimethylzinc

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Dimethylzinc, also known as Zinc methyl, DMZ, or DMZn is a colorless mobile liquid Zn(CH3)2, formed by the action of methyl iodide on zinc at elevated temperature or on zinc sodium alloy.
:2Zn + 2CH3I → Zn(CH3)2 + ZnI2
The sodium assists the reaction of the zinc with the methyl iodide. Zinc iodide is formed as a byproduct.
It has a disagreeable odor, and is pyrophoric. It has been of great importance in the synthesis of organic compounds. It is soluble in alkanes and often sold as a solution in hexanes.
It belongs to the large series of similar compounds such as diethylzinc.
==History==
This substance was first prepared by Edward Frankland during his work with Robert Bunsen in 1849 at the University of Marburg. After heating a mixture of zinc and methyl iodide in an airtight vessel, a flame burst out when the seal was broken. In the laboratory, this synthesis method remains unchanged today, except that copper or copper compounds are used to activate the zinc.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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