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|Section2= |Section3= }} Dimethylzinc, also known as Zinc methyl, DMZ, or DMZn is a colorless mobile liquid Zn(CH3)2, formed by the action of methyl iodide on zinc at elevated temperature or on zinc sodium alloy. :2Zn + 2CH3I → Zn(CH3)2 + ZnI2 The sodium assists the reaction of the zinc with the methyl iodide. Zinc iodide is formed as a byproduct. It has a disagreeable odor, and is pyrophoric. It has been of great importance in the synthesis of organic compounds. It is soluble in alkanes and often sold as a solution in hexanes. It belongs to the large series of similar compounds such as diethylzinc. ==History== This substance was first prepared by Edward Frankland during his work with Robert Bunsen in 1849 at the University of Marburg. After heating a mixture of zinc and methyl iodide in an airtight vessel, a flame burst out when the seal was broken. In the laboratory, this synthesis method remains unchanged today, except that copper or copper compounds are used to activate the zinc. 抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)』 ■ウィキペディアで「dimethylzinc」の詳細全文を読む スポンサード リンク
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