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A dithiocarbamate is a functional group in organic chemistry. It is the analog of a carbamate in which both oxygen atoms are replaced by sulfur atoms. Sodium diethyldithiocarbamate is a common example. Dithiocarbamates and their derivatives are widely used in the vulcanization of rubber.〔Hans-Wilhelm Engels et al., "Rubber, 4. Chemicals and Additives" in ''Ullmann's Encyclopedia of Industrial Chemistry'', 2007, Wiley-VCH, Weinheim. 〕 ==Formation and reactions== Many primary and secondary amines react with carbon disulfide and sodium hydroxide to form dithiocarbamate salts:〔 :R2NH + CS2 + NaOH → R2NCS2−Na+ + H2O Ammonia reacts with CS2 similarly: :2 NH3 + CS2 → H2NCS2−NH4+ Dithiocarbamate salts are pale colored solid that are soluble in water and polar organic solvents. 抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)』 ■ウィキペディアで「dithiocarbamate」の詳細全文を読む スポンサード リンク
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