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efflorescence : ウィキペディア英語版
efflorescence

In chemistry, efflorescence (which means "to flower out" in French) is the migration of a salt to the surface of a porous material, where it forms a coating. The essential process comprises the dissolving of an internally-held salt in water, or occasionally in another solvent. The water, with the salt now held in solution, migrates to the surface, then evaporates, leaving a coating of the salt.
In what has been described as "primary efflorescence," the water is the invader and the salt was already present internally. Some people describe a reverse process, where the salt is originally present externally and is then carried inside in solution, as "secondary efflorescence." However, others would give this latter phenomenon another name entirely.
Efflorescences can occur in natural and built environments. On porous construction materials it may present a cosmetic outer problem only (primary efflorescence causing staining), but can sometimes indicate internal structural weakness (migration/degradation of component materials).
==Examples==
# A 5 molar concentration aqueous droplet of NaCl will spontaneously crystallize at 45% relative humidity (298 K) to form an NaCl cube by the mechanism of homogeneous nucleation. The original water is released to the gas phase.
# Gypsum (CaSO4.2H2O) is a hydrate solid that, in a sufficiently dry environment, will give up its water to the gas phase and form anhydrite (CaSO4).
# Copper(II) sulfate (bluestone) (CuSO4.5H2O) is a blue crystalline solid that when exposed to air, slowly loses water of crystallization from its surface to form a white layer of anhydrous copper(II) sulfate.
#sodium carbonate deca hydrate will lose water when exposed to air.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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