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guaiacol : ウィキペディア英語版
guaiacol

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Guaiacol is a naturally occurring organic compound with the formula C6H4(OH)(OCH3), first isolated by Otto Unverdorben in 1826. Although it is biosynthesized by a variety of organisms,〔See for example, 〕 this yellowish aromatic oil is usually derived from guaiacum or wood creosote. Samples darken upon exposure to air and light. Guaiacol is present in wood smoke, resulting from the pyrolysis of lignin. The compound contributes to the flavor of many compounds, e.g., roasted coffee.
==Preparation==
In industry, guaiacol is produced by methylation of catechol, e.g., using potash and dimethyl sulfate:〔Helmut Fiege, Heinz-Werner Voges, Toshikazu Hamamoto, Sumio Umemura, Tadao Iwata, Hisaya Miki, Yasuhiro Fujita, Hans-Josef Buysch, Dorothea Garbe, Wilfried Paulus "Phenol Derivatives" Ullmann's Encyclopedia of Industrial Chemistry, Wiley-VCH, Weinheim, 2002. 〕
:C6H4(OH)2 + (CH3O)2SO2 → C6H4(OH)(OCH3) + HO(CH3O)SO2

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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