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|Section2= |Section3= }} Hexachlorobutadiene, Cl2C=C(Cl)C(Cl)=CCl2, is a colorless liquid at room temperature that has an odor similar to that of turpentine. It is a chlorinated aliphatic diene with niche applications but is most commonly used as a solvent for other chlorine-containing compounds.〔Manfred Rossberg et al. "Chlorinated Hydrocarbons," Ullmann's Encyclopedia of Industrial Chemistry, Wiley-VCH Verlag GmbH & Co, 2006, 〕〔Kenric A. Marshall, "Chlorocarbons and Chlorohydrocarbons, Survey," Kirk-Othmer Encyclopedia of Chemical Technology, John Wiley & Sons Inc, 2003, 〕 ==Synthesis== Hexachlorobutadiene, or HCBD, is primarily produced in chlorinolysis plants as a by-product in the production of carbon tetrachloride and tetrachloroethene. Chlorinolysis is a radical chain reaction that occurs when hydrocarbons are exposed to chlorine gas under pyrolytic conditions. The hydrocarbon is chlorinated and the resulting chlorocarbons are broken down. This process is analogous to combustion, but with chlorine instead of oxygen.〔〔Peter Schmittinger et al. "Chlorine," Ullmann's Encyclopedia of Industrial Chemistry, Wiley-VCH Verlag GmbH & Co, 2006, 〕 Hexachlorobutadiene occurs as a by-product during the chlorinolysis of butane derivatives in the production of both carbon tetrachloride and tetrachloroethene. These two commodities are manufactured on such a large scale, that enough HCBD can generally be obtained to meet the industrial demand. Alternatively, hexachlorobutadiene can be directly synthesized via the chlorination of butane or butadiene.〔〔 抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)』 ■ウィキペディアで「hexachlorobutadiene」の詳細全文を読む スポンサード リンク
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