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hexafluoroacetone : ウィキペディア英語版
hexafluoroacetone
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Hexafluoroacetone is a chemical compound with the formula CF3-CO-CF3. It is structurally similar to acetone, however its reactivity is markedly different. It comes in the form of a colourless, hygroscopic, nonflammable, highly reactive gas characterized by a musty odour.〔(CDC - NIOSH Pocket Guide to Chemical Hazards )〕 The most common form of this substance is hexafluoroacetone sesquihydrate (1.5 H2O), which is a geminal diol.
==Synthesis and reactions==
(CF3)2CO is prepared in a two step process from perfluoropropene. In the first step KF catalyzes the reaction of the alkene with elemental sulfur to give the 1,3-dithete ()2. This species is then oxidized by iodate to give (CF3)2CO.

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