| 翻訳と辞書 |
hopanoids
Hopanoids are natural pentacyclic compounds (containing five rings) based on the chemical structure of hopane. The first known triterpenoid of the class, hydroxyhopanone, was isolated by two chemists at The National Gallery, London working on the chemistry of dammar gum, a natural resin used as a varnish for paintings. The name hopane was derived from the genus ''Hopea'' (a source of the resin) itself named after John Hope, the botanist. Since this first finding, however, hopanoids have been found to be present in nature in vast amounts as components of bacteria and other primitive organisms. A range of hopanoids are found in petroleum reservoirs, where they are used as biological markers. Hopanoids are not detected in archaea.〔(【引用サイトリンク】 The AOCS Lipid Library. Hopanoids )〕
== Biological role ==
Hopanoids modify plasma membrane properties, like fluidity and formation of liquid ordered domains, influencing membrane permeability, rigidity and other characteristics in bacteria, similarly as sterols (like cholesterol) do in eukaryotes. This relationship between biochemical structure and cellular function can be seen in the similarity of the basic structures of diploptene, a hopanoid compound found in some bacterial cell membranes, and cholesterol, a sterol compound found in eukaryotic membranes.〔 In many bacteria hopanoids may play roles in the adjustment of cell membrane permeability in adaptation to extreme environmental conditions. They are formed in the aerial hyphae (spore bearing structures) of the prokaryotic soil bacteria ''Streptomyces'', where they are thought to minimise water loss across the membrane to the air. In the actinomycete ''Frankia'', the hopanoids in diazovesicle membranes likely restrict the entry of oxygen by making the lipid bilayer more tight and compact.
抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』
■ウィキペディアで「hopanoids」の詳細全文を読む
スポンサード リンク
| 翻訳と辞書 : 翻訳のためのインターネットリソース |
Copyright(C) kotoba.ne.jp 1997-2016. All Rights Reserved.
|
|