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hureaulite
Hureaulite is a manganese phosphate with the formula Mn2+5(PO3OH)2(PO4)2·4H2O. It was discovered in 1825 and named in 1826 for the type locality, Les Hureaux, Saint-Sylvestre, Haute-Vienne, Limousin, France. It is sometimes written as huréaulite, but the IMA does not recommend this for English language text.〔Burke, E. A. J. (2008): Tidying up Mineral Names: An IMA scheme for Suffixes, Hyphens and Diacritical Marks. Mineralogical Record, 39, 134〕 A complete series exists from lithiophilite, LiMn2+PO4 to triphylite, LiFe2+PO4, including hureaulite, strengite, FePO4·2H2O, stewartite, Mn2+Fe3+2(OH,PO4)2·8H2O, and sicklerite, (LiMn2+,Fe3+)PO4.〔Murdoch, Joseph (1943) Crystallography of Hureaulite. American Mineralogist 28: 19-24〕 ==Environment== Hureaulite is a secondary mineral occurring in granite pegmatites.〔 At the type locality it occurs in a zone of altered triphylite, LiMn2+PO4, in pegmatite. Typically occurs very late in the sequence of formation of secondary phosphate minerals.〔Moore, P B, and Araki, T (1973) Hureaulite: its atomic arrangement. American Mineralogist 58: 302-307.〕 Associated at the type locality with vivianite, Fe2+3(PO4)2·8H2O; rockbridgeite, Fe2+Fe3+4(PO4)3(OH)5; heterosite, (Fe3+,Mn3+)PO4 and cacoxenite, Fe3+24AlO6(PO4)17(OH)12·17H2O. It can be synthesised;〔Gerault, Y, Riou, A, and Cudennec, Y (1987) Acta Crystallographica (C) 43:1829〕 most natural hureaulites are Mn-rich compounds but extensive (Mn,Fe) solution is known for synthetic material.〔
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