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isoprenol : ウィキペディア英語版
isoprenol

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Isoprenol, also known as 3-methylbut-3-en-1-ol, is a hemiterpene alcohol. It is produced industrially as an intermediate to 3-methylbut-2-en-1-ol (prenol): global production in 2001 can be estimated as 6–13 thousand tons.〔. Major produce in a world is BASF(Germany) and Kuraray(Japan).〕
Isoprenol is produced by the reaction between isobutene (2-methylpropene) and formaldehyde.
The thermodynamically preferred isomer with the more substituted double bond cannot be directly formed in this reaction, but isomerization yields the desired product:
The reaction is catalyzed by any species which can form an allyl complex without excessive hydrogenation of the substrate, for example poisoned palladium catalysts.〔See, e.g., .〕
==Notes==


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